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Until recently, oral glutathione was thought to be ineffective at raising intracellular levels of glutathione, due to the molecules being lost during digestion
Steric hindrance from the increased side-chain volume of E14 Cagri and R17 Cagri promotes a shift of the -helix of Cagri away from ECL2 and a slight expansion of the peptide binding pocket at the extracellular side of the CTR TM domain, relative to those observed with rAmy/San385-bound AMYR complexes
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