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Additionally, two -carotenes, four manganese ions, three or four Ca 2+ ions (one bound to Mn 4 CaO 5 ), three chloride (Cl ) ions, and one carbonate (CO 3 2 ) or bicarbonate (HCO 3 ) ion are bound near the non-heme iron, participating in Q B protonation during its reduction by Q A (Shevela et al., 2012)