Conversely, the formal LUMO has a larger contribution from cyanocobalamins electronic density and a smaller one from the glutathione monoanion (Fig
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Its molecular size, disulfide bond architecture, and surface chemistry make solvent and technique selection particularly important
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Improper storage causes irreversible peptide degradation: temperatures above 30C denature protein structure within 2 hours, freezing reconstituted peptides creates ice crystals that aggregate peptide molecules, and storing lyophilised vials in humid environments introduces moisture that hydrolyzes peptide bonds even before reconstitution