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Those are all relevant and very important questions
While the second-order rate constants of PfGrx C88S and PfGrx C32S/C88S for GSSG are one order of magnitude higher than for bulky roGFP2(SSG), the rate constant for the glutathionylation of PfGrx C32S/C88S by GSSG is twice that with GSSCys (Table 1) 14
They serve different purposes and should not be conflated, though some researchers incorporate both categories into comprehensive protocols for muscle growth and athletic performance
Aoyagi T, Aoyama T, Kojima F, Matsuda N, Maruyama M, Hamada M et al
Cell Death Dis 2012
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