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Glutathione is often called the master antioxidant because, unlike other antioxidants such as vitamin C or vitamin E that are consumed in a single interaction with a free radical, glutathione can be regenerated and recycled by the enzyme glutathione reductase

This could theoretically affect DNA methylation, gene expression, and other processes dependent on methylation

Simultaneously, even well-stored peptides undergo gradual hydrolysis, a chemical reaction with water that cleaves peptide bonds and creates inactive fragments

Hurcomb JD, et al

That seems to be the threshold where cognitive benefits kick in Creatine specifically shines cognitively under stress