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In the oxidative half of the mechanism, Cys63 nucleophilically attacks the nearest sulfide unit in the glutathione disulfide (GSSG) molecule, which creates a mixed disulfide bond (GS-Cys58) and a GS- anion
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This is established fact, supported by the SURMOUNT trial series with thousands of participants
2018, Nov, 2;17(11):373039 Ozcariz E, Guardiola M, Amig N, Rojo-Martnez G, Valds S, Rehues P, et al
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